Skip to Main content Skip to Navigation
Journal articles

A new biomimetic-like aromatization of the cyclic end groups of terpenoids with stereospecific migration of one of the methyl groups: a convenient route to isorenieratene (.vphi.,.vphi.-carotene)

Abstract : The synthesis of isorenieratene, a natural carotenoid isolated from the marine sponge Reniera japonica and from some anoxygenic phototrophic bacteria or nonphotosynthetic actinomycetes, was performed from α-, β- and retro-ionones. In this series of cyclohexenes, this synthesis is the first to include a one-pot aromatization of the cyclic end group with concomitant regioselective migration of one Me group from the gem di-Me functionality. [on SciFinder(R)]
Document type :
Journal articles
Complete list of metadatas

https://hal.univ-reunion.fr/hal-01188167
Contributor : Claire Tessier <>
Submitted on : Friday, August 28, 2015 - 3:09:20 PM
Last modification on : Thursday, May 14, 2020 - 7:58:28 AM

Links full text

Identifiers

Citation

Alain Valla, Zo Andriamialisoa, Benoist Valla, Roger Labia, Regis Le Guillou, et al.. A new biomimetic-like aromatization of the cyclic end groups of terpenoids with stereospecific migration of one of the methyl groups: a convenient route to isorenieratene (.vphi.,.vphi.-carotene). European Journal of Organic Chemistry, Wiley-VCH Verlag, 2007, 2007 (4), pp.711--715. ⟨10.1002/ejoc.200600794⟩. ⟨hal-01188167⟩

Share

Metrics

Record views

123