Precisely Designed Difunctionalized Cyclodextrin Produces a Solid‐State Organic Porous Hierarchical Supramolecular Assembly - Chimie des Polymères Access content directly
Journal Articles Chemistry - A European Journal Year : 2023

Precisely Designed Difunctionalized Cyclodextrin Produces a Solid‐State Organic Porous Hierarchical Supramolecular Assembly

Abstract

Regioselective di-functionalization of a cyclodextrin allows hydrophobic domains to be directed in a geometrically controlled manner. This controlled orientation ultimately gives access to an original hierarchical assembly in the solid state. This assembly spans over three levels of hierarchy which are governed by synergistic host-guest inclusions, directed hydrophobic effect and hydrogen bonding. This combination of interactions precisely positioned in space through regioselective functionalization of a cyclodextrin creates a porous organic architecture.
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Dates and versions

hal-04142697 , version 1 (27-06-2023)

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Dmitri Colesnic, Pedro J Hernando, Lise‐marie Chamoreau, Laurent Bouteiller, Mickaël M Ménand, et al.. Precisely Designed Difunctionalized Cyclodextrin Produces a Solid‐State Organic Porous Hierarchical Supramolecular Assembly. Chemistry - A European Journal, 2023, 29 (35), ⟨10.1002/chem.202300150⟩. ⟨hal-04142697⟩
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