Synthesis of a New C-15 Phosphorus Ylide Used for the Preparation of Some β-End-Group Retinoid Derivatives

Alain Valla; Nathalie Méheux; Dominique Cartier; Benoist Valla; Laurent Dufossé; Roger Labia

Synthesis of a New C-15 Phosphorus Ylide Used for the Preparation of Some β-End-Group Retinoid Derivatives

Alain Valla ¹ Nathalie Méheux Dominique Cartier Benoist Valla Laurent Dufossé ² Roger Labia

1 Chimie et biologie des substances naturelles

2 LCSNSA - Laboratoire de Chimie des Substances Naturelles et des Sciences des Aliments

Abstract : A synthesis of a new C-15 phosphorus ylide from a C-14 enaminone is reported. This reagent, which undergoes selective 1,2- or 1,4-additions with saturated and unsaturated aldehydes, may find some synthetic use for the preparation of β-end-group retinoid derivatives.

Document type :

Journal articles

Domain :

Chemical Sciences

Complete list of metadatas

http://hal.univ-reunion.fr/hal-01188126
Contributor : Claire Tessier <>
Submitted on : Friday, August 28, 2015 - 3:07:07 PM
Last modification on : Monday, September 2, 2019 - 9:43:20 AM

Synthesis of a New C-15 Phosphorus Ylide Used for the Preparation of Some β-End-Group Retinoid Derivatives

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Synthesis of a New C-15 Phosphorus Ylide Used for the Preparation of Some β-End-Group Retinoid Derivatives

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