Synthesis of a New C-15 Phosphorus Ylide Used for the Preparation of Some β-End-Group Retinoid Derivatives

Abstract : A synthesis of a new C-15 phosphorus ylide from a C-14 enaminone is reported. This reagent, which undergoes selective 1,2- or 1,4-additions with saturated and unsaturated aldehydes, may find some synthetic use for the preparation of β-end-group retinoid derivatives.
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https://hal.univ-reunion.fr/hal-01188126
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Submitted on : Friday, August 28, 2015 - 3:07:07 PM
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Alain Valla, Nathalie Méheux, Dominique Cartier, Benoist Valla, Laurent Dufossé, et al.. Synthesis of a New C-15 Phosphorus Ylide Used for the Preparation of Some β-End-Group Retinoid Derivatives. Synthetic Communications, Taylor & Francis: STM, Behavioural Science and Public Health Titles, 2010, 41 (2), pp.184--190. ⟨10.1080/00397910903531938⟩. ⟨hal-01188126⟩

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